New Book: ‘Water, Energy, and Environment – A Primer’

After a long hiatus from blogging while I worked on a new book, I am pleased to announce that the book ‘Water, Energy, and Environment – A Primer’ will be published by International Water Association Publishing (IWAP) on February 18th (2019). It will be available in both printed and digital form, and the digital version will be downloadable for free as an Open Access (OA) document.

To access the free digital version go to IWAP’s OA website on Twitter: https://twitter.com/IWAP_OA.

Attached below is front material from the book, its preface and table of contents. Designed to serve as a basic and easily read introduction to the linked topics of water, energy, and environment, it is just under 200 pages in length, a convenient size to throw into a folder, a briefcase, or a backpack. Its availability as an OA document means that people all over the world with access to the internet will have access to the book and its 10 chapters.

With the completion of the book I plan to return to a regular schedule of blogging.
…………………………..
Contents
Preface ………………………………….. xi
Acknowledgement ……………………….. xv
Acronyms ……………………………… xvii
Epigraph ……………………………….. xxi
Chapter 1
Water and its global context …………………. 1
1.1 Earth’s Water Resources . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Saline Water and Desalination Processes . . . . . . . . . . . 2
1.3 Energy Requirements and Costs of Desalination . . . . . 5
1.4 Demand for Freshwater . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.5 Implications of Limited Access to Freshwater . . . . . . . . . 9
1.6 Actions to Increase Access to Freshwater . . . . . . . . . . 10
1.7 Gender Equity Issues . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Chapter 2
Energy and its global context ……………….. 13
2.1 Energy’s Role in Society . . . . . . . . . . . . . . . . . . . . . . . . . 13
2.2 Energy Realities . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
2.3 What is Energy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
2.4 Energy Trends . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2.4.1 Important questions . . . . . . . . . . . . . . . . . . . . . . . 18
2.4.2 How is energy used? . . . . . . . . . . . . . . . . . . . . . . 18
2.4.3 Electrification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Chapter 3
Exploring the linkage between water
and energy ……………………………….. 23
3.1 Indirect Linkages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
3.2 The Policy Linkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
3.3 The Conundrum . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
3.4 Addressing the Conundrum . . . . . . . . . . . . . . . . . . . . . . . 26
3.5 The Need for Partnership . . . . . . . . . . . . . . . . . . . . . . . . . 27
Chapter 4
Energy production and its consequences for
water and the environment …………………. 29
4.1 Impacts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
4.2 More on Climate Change . . . . . . . . . . . . . . . . . . . . . . . . . 32
4.3 Environment and Religion . . . . . . . . . . . . . . . . . . . . . . . . 33
4.3.1 The theocentric worldview . . . . . . . . . . . . . . . . . 33
4.3.2 The anthropocentric worldview . . . . . . . . . . . . . 34
4.3.3 Other worldviews . . . . . . . . . . . . . . . . . . . . . . . . . 34
Chapter 5
Energy options ……………………………. 37
5.1 Fossil Fuels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
5.2 Nuclear Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
5.3 Geothermal Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
5.4 The Sun . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
5.5 Energy Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
5.5.1 Energy demand . . . . . . . . . . . . . . . . . . . . . . . . . . 40
vi Water, Energy, and Environment – A Primer
5.5.2 Implementation . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
5.5.3 Saving energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
5.5.4 Accelerating implementation . . . . . . . . . . . . . . . 43
5.5.5 Energy Star . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
5.5.6 The lighting revolution . . . . . . . . . . . . . . . . . . . . . 45
5.5.7 Energy efficiency in buildings . . . . . . . . . . . . . . . 48
5.5.7.1 Zero energy buildings . . . . . . . . . . . . . 48
5.5.7.2 Electrochromic windows . . . . . . . . . . . 52
5.6 Energy Efficiency in Industry . . . . . . . . . . . . . . . . . . . . . . 54
5.7 Energy Efficiency in Transportation . . . . . . . . . . . . . . . . 56
Chapter 6
Fossil fuels ………………………………. 61
6.1 Coal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
6.1.1 Carbon capture and sequestration . . . . . . . . . . 63
6.1.2 A conundrum . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
6.2 Petroleum . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
6.2.1 Oil spills . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
6.2.2 Peak oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
6.3 Natural Gas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
6.3.1 Methane hydrates . . . . . . . . . . . . . . . . . . . . . . . . . 77
6.3.2 Fracking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
Chapter 7
Nuclear power ……………………………. 85
7.1 Nuclear Fission . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
7.1.1 Fission fundamentals . . . . . . . . . . . . . . . . . . . . . . 85
7.1.2 Introduction to nuclear issues . . . . . . . . . . . . . . . 87
7.1.3 Issues . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
7.2 Nuclear Fusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
7.2.1 Fusion fundamentals . . . . . . . . . . . . . . . . . . . . . . 91
7.2.2 Numbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
7.2.3 Barriers to Fusion . . . . . . . . . . . . . . . . . . . . . . . . . 94
7.2.4 Pros and cons . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
7.2.5 Thoughts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95
Chapter 8
Renewable energy ………………………… 97
8.1 The Sun’s Energy Source and Radiation
Spectrum . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
8.2 Direct Solar Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
8.2.1 Photovoltaics . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
8.2.2 Concentrating solar power (CSP) . . . . . . . . . . 108
8.2.2.1 Power tower . . . . . . . . . . . . . . . . . . . . 109
8.2.2.2 Linear concentrator . . . . . . . . . . . . . . 110
8.2.2.3 Dish engine . . . . . . . . . . . . . . . . . . . . . 111
8.2.2.4 CSTP history . . . . . . . . . . . . . . . . . . . 112
8.2.2.5 Advantages and disadvantages . . . 112
8.2.2.6 Thermal storage . . . . . . . . . . . . . . . . . 113
8.2.2.7 Current status . . . . . . . . . . . . . . . . . . . 114
8.2.2.8 Concentrating photovoltaics (CPV) . 115
8.3 Solar Power Satellite (SPS) System . . . . . . . . . . . . . . 116
8.4 Hydropower and Wind Energy . . . . . . . . . . . . . . . . . . . 119
8.4.1 Hydropower . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
8.4.2 Wind energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
8.4.2.1 Onshore wind . . . . . . . . . . . . . . . . . . . 121
8.4.2.2 History . . . . . . . . . . . . . . . . . . . . . . . . . 124
8.4.2.3 An onshore limitation . . . . . . . . . . . . . 124
8.4.2.4 Offshore wind . . . . . . . . . . . . . . . . . . . 125
8.5 Biomass Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129
8.5.1 Sources of biomass . . . . . . . . . . . . . . . . . . . . . . 129
8.5.2 Wood . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 129
8.5.3 Biofuels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130
8.5.4 Algae . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
8.5.5 Biochar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
8.5.6 The future . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
8.6 Geothermal Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
8.6.1 Sources of geothermal energy . . . . . . . . . . . . . 134
8.6.2 Manifestations of geothermal energy . . . . . . . 135
8.6.3 Uses of geothermal energy . . . . . . . . . . . . . . . . 135
8.6.3.1 Geothermal power generation . . . . . 136
8.6.3.2 Ground-source heat pumps . . . . . . . 138
8.6.4 An unusual source of geothermal energy . . . . 140
Ocean Energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
8.7.1 Wave energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
8.7.1.1 Wave energy conversion
devices . . . . . . . . . . . . . . . . . . . . . . . . 142
8.7.1.2 Potential and pros and cons . . . . . . . 143
8.7.2 Ocean current energy . . . . . . . . . . . . . . . . . . . . 144
8.7.3 Tidal energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
8.7.3.1 Barrage . . . . . . . . . . . . . . . . . . . . . . . . 146
8.7.3.2 History . . . . . . . . . . . . . . . . . . . . . . . . . 147
8.7.3.3 Environmental impacts . . . . . . . . . . . 147
8.7.4 Ocean thermal energy conversion (OTEC) . . 147
8.7.4.1 Barriers . . . . . . . . . . . . . . . . . . . . . . . . 148
8.7.4.2 OTEC technologies . . . . . . . . . . . . . . 148
8.7.4.3 Other cold water applications . . . . . . 149
8.7.4.4 OTEC R&D . . . . . . . . . . . . . . . . . . . . . 149
Chapter 9
Energy storage …………………………… 151
9.1 Storage and Grids . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
9.2 Types of Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152
9.2.1 Traditional and advanced batteries . . . . . . . . . 153
9.2.1.1 Lead–acid . . . . . . . . . . . . . . . . . . . . . . 153
9.2.1.2 Sodium sulfur . . . . . . . . . . . . . . . . . . . 153
9.2.1.3 Nickel–cadmium . . . . . . . . . . . . . . . . . 154
9.2.1.4 Lithium-ion . . . . . . . . . . . . . . . . . . . . . 154
9.2.1.5 Supercapacitors . . . . . . . . . . . . . . . . . 155
9.2.2 Flow batteries . . . . . . . . . . . . . . . . . . . . . . . . . . . 156
9.2.3 Flywheels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
9.2.4 Superconducting magnetic energy
storage (SMES) . . . . . . . . . . . . . . . . . . . . . . . . . 158
9.2.5 Compressed air energy storage (CAES) . . . . 159
9.2.6 Pumped storage . . . . . . . . . . . . . . . . . . . . . . . . . 160
9.2.7 Thermal storage . . . . . . . . . . . . . . . . . . . . . . . . . 161
9.3 Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
9.4 Costs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162
9.5 Fundamental Change . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Chapter 10
Policy considerations …………………….. 165
10.1 Important Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . 166
10.1.1 Is there a physical basis for understanding
global warming and climate change? . . . . . . 166
10.1.2 Is there documented evidence for global
warming and climate change? . . . . . . . . . . . . 168
10.1.3 Can global warming and climate change be
attributed to human activities, and what are
those activities? . . . . . . . . . . . . . . . . . . . . . . . . 170
10.1.4 What are the potential short- and long-term
impacts of global warming and climate
change with respect to water supply,
environment, and health? What is the
anticipated time scale for these
impacts? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 172
10.1.5 What can be done to mitigate the onset
and potential impacts of global warming
and climate change? . . . . . . . . . . . . . . . . . . . . 179
References ……………………………… 183
Index …………………………………… 189

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Preface
This book springs from my strong conviction that clean water and clean energy are the critical elements of long-term global sustainable development. I also believe that we are experiencing the beginning of an energy revolution in these early years of the 21st century. Providing clean water requires energy, and providing clean energy is essential to reducing the environmental impacts of energy production and use. Thus, I see a nexus – a connection, a causal link – among water, energy, and environment. In recent years we have adopted the terminology of the water-energy nexus for the intimate relationship between water and energy, and similarly we can apply the term nexus to the close connections among water, energy, and environment. Thisuse of the term nexus can be, and has been, extended to include the related issues of food production and health. Dealing with, and writing about, a two-element nexus is difficult enough. In this book, I will limit my analysis and discussion to the three-element water -energy-environment nexus and leave the discussion of other possible nexus elements to those more qualified to comment.

This book also springs from my observation that while there are many existing books of a more-or-less technical nature on the three elements of this nexus, a book addressing each of them and their interdependencies in a college-level primer for a broad global and multidisciplinary audience would be valuable. Consideration of these and related issues, and options for addressing them, will be priorities for all levels of government. They will also be priorities for many levels of the
private sector in the decades ahead, both in developing and developed nations. A handbook-style primer that provides an easily read and informative introduction to, and overview of, these issues will contribute broadly to public education. It will assist governments and firms in carrying out their responsibilities to provide needed services and goods in a sustainable manner, and help to encourage young people to enter these fields. It will serve as an excellent mechanism for exposure of experts in other fields to the issues associated with the water-energy-environment nexus. Further, in addition to the audiences mentioned above, target audiences include economists and others in the finance communities who will analyze and provide the needed investment funds, and those in the development community responsible for planning and delivering services to underserved populations.
The book is organized as follows: the first chapter will be devoted to the concept of nexus and how the three elements, water, energy, and environment, are inextricably linked. This recognition leads to the conclusion that if society is to optimize their contributions to human and planetary welfare they must be addressed jointly. No longer must policy for each of these elements be considered in its own silo. Chapters 2 and 3 will be devoted to spelling out global contexts for water and energy issues, respectively. Chapter 4, on related environmental issues, will address the issues of water contamination, oil spills, fracking, radioactive waste storage, and global warming/
climate change. Chapter 5 will be a discussion of energy efficiency – i.e., the wise use of energy – and its role in limiting energy demand and its associated benefits. Chapter 6 will focus on the basics of fossil fuels – coal, oil, natural gas – which today dominate global energy demand. Chapter 7 will discuss nuclear-fission-powered electricity production, which today accounts for 10% of global electricity. It will also discuss the prospects for controlled nuclear fusion. Chapter 8 will discuss the broad range of renewable energy technologies – wind, solar,hydropower, biomass, geothermal, ocean energy – which are the basis of the now rapidly emerging energy revolution. Chapter 9 will discuss the closely related issue of energy storage. Finally, Chapter 10 will address
policy issues associated with water, energy, and environment, discuss policy history and options, and provide recommendations.

Methane Hydrates: The Granddaddy of Fossil Fuels

For those of us who follow energy issues closely, a long-standing, persistent question has been: Are methane hydrates for real? Are they a realistically large potential energy resource? The answer seems to be yes.

Thirty years ago the information available to answer these questions was not available. Today the literature on methane hydrates (also known as methane clathrates, methane ice, fire ice) is extensive and growing. This blog post attempts to capture the main points I came away with in a detailed review of the subject. To this energy wonk it was both fascinating and disturbing – fascinating in nailing down a lot of details about a potentially new and very large energy resource, and disturbing in that it again raises serious concerns for me about our lack of a national energy policy. I will explain further.

First a word about clathrates and hydrates: clathrate is a general term that describes solids in which gases are trapped within any kind of chemical cage, while hydrate is the specific term used when that cage is made of water molecules. In methane hydrates the trapped gas is methane, the principal constituent of natural gas and the simplest known hydrocarbon (CH4). CO2 and other gas hydrates are also possible and are speculated to exist on Mars, other planets and their moons. On our home planet most of the hydrates are filled with methane, and there is lots of it.

Methane hydrates form as a solid similar to ice under the right conditions of methane and water availability, temperature (low) and pressure (high).

image

They are fragile, easily destabilized (i.e., returning to separated water and no-longer-trapped CH4) by pressure and/or temperature changes, and are found most often within, and occasionally on top of, sediments on the ocean floors. They are called ‘fire ice’ because they can be lit by a match:

image

The most common type of methane hydrate (>99%) has a density of 0.9gm/cc or just slightly less than that of water, so it can float. One liter of the fully saturated solid would yield 120 grams of methane or 169 liters of gas at standard temperature and pressure. It forms in the presence of water and methane under conditions found in the oceans, deep lakes, and under ice caps that fall within a gas hydrate stability zone defined by the following phase diagram:

image

The seafloor of most of the world’s oceans fall within the hydrate stability zone. Methane hydrates are also found in Arctic permafrost and continental deposits in sandstone and limestone in Alaska and Siberia. These deposits may cover even larger reservoirs of methane gas beneath.

There are two sources for this methane: thermogenic methane that is formed deep in the earth by the same thermal/high pressure processes that convert organic matter to coal, oil and gas and which leaks upward toward the ocean floor where it forms hydrates when it comes in contact with highly pressurized cold (0-2C) water; and methane generated by microbes degrading organic matter (plankton) in low oxygen environments in sediments. This latter process is the dominant source of CH4 for methane hydrates.

Why are methane hydrates important? The DOE’s Energy Information Administration estimates that such hydrates contain more carbon (and therefore more potential fuel) than all other fossil fuels combined. It also reports that these hydrates could hold as much as 10,000-100,000 trillion cubic feet (Tcf) of natural gas. To put these numbers into perspective, total global consumption of natural gas is currently 120 Tcf. We are talking about a LARGE potential energy resource.

image

It is also widely distributed as shown in the following map and has the potential to be an indigenous resource for many countries:

image

It is also straightforward to separate the methane from its hydrate cage by heating it up or reducing its pressure. Both techniques have been demonstrated and are currently being explored actively in public and private research programs in many countries. The production problems arise when one tries to convert this resource into a marketable commodity at a reasonable cost. There are also serious environmental questions about methane hydrates because methane is a powerful greenhouse gas in its own right and releases CO2, another greenhouse gas, when it is burned. Both issues are discussed below.

The presence of most of the hydrates on the deep sea floor and in sediments just beneath it means that extraction must be carried out under extreme conditions of depth, pressure and temperature. The methane concentrations are also spread out, increasing the harvesting costs, undersea infrastructure costs, and transmission costs of bringing the gas to the surface. The fragility of the hydrates also requires that they be handled carefully, avoiding a sudden release of gas and resultant overpressurization.

The environmental problems reflect concern about methane’s strong greenhouse gas properties (20 times more effective at trapping heat than CO2) and, when oxidized (either by combustion or aerobic conversion), that it releases CO2, another, although less powerful, greenhouse gas. A saving grace is that in its pure CH4 form in the atmosphere methane’s half life is 7.5 years. CO2 on the other hand has an atmospheric half life of hundreds of years. Leakage of methane from pipelines and other infrastructure is also a concern, as it is for other sources of natural gas.

Another problem for methane production from hydrates is the fact that shale gas via fracking is just coming into its own as a major source of competitive natural gas, thus reducing the commercial incentive to develop the hydrates. Unless the cost of producing methane from hydrates can be reduced significantly this will remain an important barrier as long as shale gas is available in quantity.

The U.S. is one of several countries with an active methane hydrate R&D program. Others include Russia, India, S. Korea and Japan. Japan has been a leader in this research for many years, given its lack of indigenous energy resources and its heavy dependence on imports. Japan’s recent problems with its nuclear power plants has further increased its dependence on imported LNG and its associated costs, which are very high in the Asian market (roughly 3-4 times higher than in the U.S. market).

The U.S. program was jump-started by the passage of The National Methane Hydrates R&D Act of 2000, which requires “the development of a national methane hydrate R&D program that utilizes the talents of federal, private, and academic organizations.” The result is a joint public-private effort supported collaboratively by quite a few U.S. government departments and agencies: USGS, BLM, DOE, DOI, BOEMRE, NOAA, NRL, and NSF. Several National Laboratories (NETL, ORNL,..) are also heavily engaged.

Major arguments in favor of developing methane hydrates are the fact that it is an indigenous resource, thus enhancing national security and potentially reducing energy import costs, and the fact that natural gas can be substituted for coal in electric power plants, thus reducing carbon emissions per unit of energy produced. These are strong arguments, but raise the concern that investments in natural gas will reduce U.S. investments in energy efficiency and renewable energy. This is a serious concern in a country without an articulated energy policy that points us clearly toward a renewable energy future, and without a price on carbon emissions. This lack of a policy structure can only allow a delay in the inevitable transition to an energy economy that is increasingly dependent on renewable energy. It will also allow more carbon into the atmosphere – methane still releases carbon when burned.

In sum, the world is rich in methane, much richer than in other fossil fuels in terms of energy potential, but getting that methane to market at an affordable price is not now, and perhaps not for a long time, easily achieved. Unconventional natural gas production (shale, methane hydrates) and use also present serious greenhouse gas concerns which will require careful regulation and enforcement. It also presents important policy concerns that the U.S. Congress has so far shown a reluctance to address. We need to do better!